After refueling, turn the fuel tank cap until you hear a click. Once the cap is released, it will turn slightly in the opposite direction.

Caution
When replacing the fuel tank cap
Do not use anything but a genuine toyota fuel tank cap designed for your vehicle. Doing so may cause a fire or other incident which may result in death or serious injury.
Opening the fuel tank capGeneral information
A large number of ecu controlled systems are used in the
rav4. In general, ecu controlled systems are considered to
be very intricate, requiring a high level of technical knowledge
to troubleshoot. However, most problem checking procedures
only involve inspecting the ecu controlled system's circ ...
Luggage room light
Components
Removal
Disconnect cable from negative battery
terminal
Caution:
Wait at least 90 seconds after disconnecting the
cable from the negative (-) battery terminal to
prevent airbag and seat belt pretensioner activation.
Remove back door center garnish (see page
ed-59)
...
Fuel system
Precaution
Before working on fuel system
Do not work near an open flame.
Keep gasoline away from rubber and leather parts.
Discharge the fuel pressure before disconnecting
the fuel line to prevent gasoline from spilling out.
Refer to the following procedure.
Discharge fuel ...